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Metalloenzymes catalyse a wide variety of reactions in nature. In the thesis, I have studied the reaction mechanism of three metalloenzymes, viz. [NiFe] hydrogenase (H2ase), dimethyl sulfoxide reductase (DMSOR) and formate dehydrogenase (FDH), by theoretical methods, namely quantum mechanics (QM), combined quantum mechanical and molecular mechanics (QM/MM), as well as QM/MM thermodynamic cycle per

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We present a method to add confidence limits to level curves, drawn on a map of a Gaussian random surface, measured with or without error on a regular or irregular grid. The method is based on the conditional level crossing intensity measure for non-stationary Gaussian fields.

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Current hemophilia B treatment guidelines recommend routine prophylaxis with factor IX (FIX) replacement products, tailored to maintain plasma activity at levels that will prevent bleeds. However, plasma FIX activity may not be the primary determinant or best indicator of hemostatic efficacy due to its extravascular distribution. FIX replacement therapy has evolved to include extended half-life (E

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Patriarchal ideologies, gender equality and the conflict between the old and modern ways of life have always been topics of discussion in contemporary society. In 1925, F. Scott Fitzgerald published The Great Gatsby, when patriarchal ideologies were dominant in American society and American literature. Additionally, there is an ambivalence showing that although times were changing, the gender ster