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In this study linear free energy relationships (LFER) are applied to the relaxation of core-excited states in aliphatic CH3X compounds. There are at least two valence orbitals involved in Auger decay following C-CH3 1s -> sigma*(C-X) excitation, which may as well be localized on the substituents in this series. Therefore, the observed property cannot be strictly attached to the so-called reaction
Popular Abstract in Swedish Njurarna spelar en central roll i de förändringsprocesser som anpassar kvinnans kropp till en graviditet. Många av de förändringar som sker mot slutet av en normal graviditet, påminner om de förändringar man ser vid preeklampsi, havandeskapsförgiftning, om än mindre uttalade. Preeklampsi är ett allvarligt risktillstånd som kan uppkomma under graviditet och en av de störThe kidneys play a pivotal role in the adaptive physiology of the pregnant woman, presenting some changes at term similar to the changes found in preeclampsia – a state of increased risk of fetal and maternal morbidity and mortality. The aim of these investigations was to explore possible similarities in blood pressure regulation, renal function and structure in normal term and preeclamptic pregna
The development of biodegradable polymers from renewable resources is of importance in order to prevent the depletion of fossil fuels and the increasing emissions of carbon dioxide to the atmosphere caused by the commodity plastics of today. However, to be able to replace these non-environmentally friendly materials, production costs of biodegradable polymers have to be decreased and their physica
Affinity two-phase partitioning based on an immunoaffinity sandwich approach for the rapid and selective purification of membranes is presented in this thesis. The method was developed by studying different parameters governing the affinity partitioning of model membranes. To this end, biotinylated liposomes were used. They specifically distributed to the bottom phase of a poly (ethylene glycol)/d
In-situ nutrient sensors are now a proven technology. Having ion membranes eliminates the need for ultrafiltration, and consequently the sensors can be located at suitable places in any of the reactors. This gives the potential for new control structures for the control of nitrification, denitrification, and phosphorus removal. In the paper some examples of such controllers are demonstrated as use
This note summarizes many detailed physics studies done by the ATLAS and CMSCollab orations for the LHC, concentrating on processes involving the production of high mass states. These studies show that the LHC should be able to elucidate the mechanism of electroweak symmetry breaking and to study a variety of other topics related to physics at the TeV scale. In particular, a Higgs boson with coupl
This paper presents a study of phase noise in CMOS Colpitts and LC-tank oscillators. Closed-form symbolic formulas for the 1/f/sup 2/ phase-noise region are derived for both the Colpitts oscillator (either single-ended or differential) and the LC-tank oscillator, yielding highly accurate results under very general assumptions. A comparison between the differential Colpitts and the LC-tank oscillat
A new criterion is applied for characterization of the kinetic design of enzymes that should be favoured by a selective pressure in the direction of increased metabolic reaction flux. According to this criterion, the selectively favoured state of a metabolic sequence of enzyme reactions conforming to Michaelis-Menten kinetics is identical with the uniform one which is known to optimize reaction fl
The growing world electricity demand and environmental concerns pushes toward new technology for electricity production. Within the thermal processes for electricity production, two axis of research are being developed to meet the needs of the industry, namely using renewable fuels and new generation burners technology. The first direction is to develop new processes able to use renewable fuels. B
Meteorological investigations were carried out in forests in the southwestern part of the Swabian Alb (SW Germany) to analyze the influences of exposition and silvicultural treatment on the microclimate within various stands of beech (Fagus sylvatica L.). The measurements were taken as part of an interdisciplinary project on the effects of climate and forest management on structures and processes
Analysis of bioreactors is central for successful design and operation of biotechnical processes. The bioreactor should provide optimum conditions, with respect to temperature, pH and substrate condition, for example, besides its basic function of containment. The ability to control the substrate concentration is an important function of the bioreactor. The substrate concentration can be subject t
The aim of the present study is to examine the validity of using silicon semiconductor detectors in degraded electron beams with a broad energy spectrum and a wide angular distribution. A comparison is made with diamond detector measurements, which is the dosimeter considered to give the best results provided that dose rate effects are corrected for. Two-dimensional relative absorbed dose distribu
In experiments, the feasibility was demonstrated of generating multi-MeV electrons in a form of a collimated beam utilizing a table-top laser system delivering 200 fs pulses with P-L=1.2 TW and 10 Hz capability. The method uses the process of relativistic self-channeling in a high-density gas jet producing electron densities in the range of 3x10(19)-6x10(20) cm(-3). In a thorough investigation, an
This paper presents a 1MHz bandwidth, ΔƩ fractional-N PLL as the frequency synthesizer for LTE. A noise cancellation path composed of a novel hybrid ΔƩ DAC with 9 output bits is incorporated into the PLL in order to cancel the out-of-band phase noise caused by the quantization error. Further, a re-timing circuit is proposed to reduce the nonlinearity in the Charge Pump and provide pulse shaping si
This work presents an event-based control structure using the generalized predictive control (GPC) algorithm with actuator deadband. The main objective of this work is to limit the number of controlled system updates. In this approach, the controlled process is sampled with a constant sampling time and is updated in an asynchronous way that depends on the obtained control signal value. To achieve
By exposing photosystem II (PSII) samples to an incrementing number of excitation flashes at room temperature, followed by freezing, we could compare the Mn-derived multiline EPR signal from the S-2 oxidation state as prepared by 1, 5, 10, and 25 flashes of light. While the S-2 multiline signals exhibited by these samples differed very little in spectral shape, a significant increase of the relaxa
In an effort to find conditions favouring bioelectrocatalytic reduction of oxygen by surface-immobilised human ceruloplasmin (Cp), direct electron transfer (DET) reactions between Cp and an extended range of surfaces were considered. Exploiting advances in surface nanotechnology, bare and carbon-nanotube-modified spectrographic graphite electrodes as well as bare, thiol- and gold-nanoparticle-modi
ObjectiveTo determine whether an experienced ultrasound examiner, using good ultrasound equipment with high multifrequency probes, can discriminate between a high grade or low grade dysplastic adenoma (pT0) and very early invasive rectal cancers (pT1). Subjects and methodsSixty consecutive patients with clinically possibly pT0 or pT1 rectal tumours referred for transanal local excision underwent
BACKGROUND: In early breast cancer, variations in local treatment that substantially affect the risk of locoregional recurrence could also affect long-term breast cancer mortality. To examine this relationship, collaborative meta-analyses were undertaken, based on individual patient data, of the relevant randomised trials that began by 1995. METHODS: Information was available on 42,000 women in 78
