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The behavior of a sterically crowded neutral pincer {2,6-bis[(di-t-butylphosphino)methyll-phenyl}palladium (PCPPd) halides, PCPPdX (X = Cl, Br or I), as XB acceptors with strong halogen bond (XB) donors, iodine (I(2)), 1,4-diiodotetrafluorobenzene (F4DIBz), and 1,4-dliodooctafluorobutane (F8DIBu) were studied in the solid state. The co-crystallization experiments afforded high-quality single cryst

Proteomic screening of strawberry (Fragaria ananassa) yielded a 58% success rate in protein identification in spite of the fact that no genomic sequence is available for this species. This was achieved by a combination of MALDI-MS/MS de novo sequencing of double-derivatized peptides and indel-tolerant searching against local protein databases built on both EST and full-length nucleotide sequences.

We consider the problem of how to schedule t similar and independent tasks to be performed in a synchronous distributed system of p stations communicating via multiple-access channels. Stations are prone to crashes whose patterns of occurrence are specified by adversarial models. Work, defined as the number of the available processor steps, is the complexity measure. We consider only reliable algo

Transfer of N-15 between interacting mycelia of a wood-decomposing fungus (Hypholoma fasciculare) and an ectomycorrhizal fungus (Tomentellopsis submollis) was studied in a mature beech (Fagus sylvatica) forest. The amount of N-15 transferred from the wood decomposer to the ectomycorrhizal fungus was compared to the amount of N-15 released from the wood-decomposing mycelia into the soil solution as

The current plastic system is unsustainable and needs to change. Plastics are mainly produced from fossil feedstock, contributing to greenhouse gas emissions, and low rate of post-consumer recycling results in pollution on land and in oceans with high ecological impact, and huge loss of valuable material. There is an urgent need to find solutions for shifting the raw material base to renewable res

There is an urgent need for society to find more effective ways to reduce the impact of disastrous events. One way is to proactively increase actors’ response capability. Capability assessments play an essential role in these disaster risk management efforts. Currently, capability is assessed using indicator and index methods that focus on available resources. Such methods may not provide the best

Child perspective on being summoned to, visiting and exiting Barnahus Aim This study forms an essential part in informing effective prevention and interventions with children exposed to or at risk of domestic violence and sexual abuse, focusing on children becoming summoned, visiting and exiting Barnahus with a child perspective. Background In Sweden when custodians are under suspicion, the child

Navigation is the ability of animals to move through their environment in a planned manner. Different from directed but reflex-driven movements, it involves the comparison of the animal’s current heading with its intended heading (i.e., the goal direction). When the two angles don’t match, a compensatory steering movement must be initiated. This basic scenario can be described as an elementary nav

Advanced preservation injury (PI) after intestinal transplantation has deleterious short-and long-term effects and constitutes a major research topic. Logistics and costs favor rodent studies, whereas clinical translation mandates studies in larger animals or using human material. Despite diverging reports, no direct comparison between the development of intestinal PI in rats, pigs, and humans is

Monitoring of individual biomarkers has the potential of explaining the hazard of survival outcomes. In practice, these measurements are intermittently observed and are known to be subject to substantial measurement error. Joint modelling of longitudinal and survival data enables us to associate intermittently measured error-prone biomarkers with risks of survival outcomes and thus plays an import

Osteoarthritis (OA) remains the most challenging arthritic disorder, with a high burden of disease and no available disease-modifying treatments. Symptomatic early-stage OA of the knee (the focus of this Review) urgently needs to be identified and defined, as efficient early-stage case finding and diagnosis in primary care would enable health-care providers to proactively and substantially reduce

We examine a two-dimensional Coulomb gas consisting of n identical repelling point charges at an arbitrary inverse temperature β, subjected to a suitable external field. We prove that the gas is effectively localized to a small neighbourhood of the droplet – the support of the equilibrium measure determined by the external field. More precisely, we prove that the distance between the droplet and t

Microbial resistance to antibiotics is a growing challenge to human health. Recent evidence has indicated that antibiotic resistance can be co-selected for by exposure to heavy metals in agricultural soils. It remains unknown if this is a concern in other environments contaminated by metals. We here investigated soil microbial activities, composition and tolerance to heavy metals and antibiotics i

Because biomass is a widely available, renewable resource, its utilisation for the production of energy has great potential for reducing CO2 emissions and thereby preventing global warming. In this mini-review the `state of the art' of several fermentation processes is discussed, starting with the most advanced process of ethanol production. This is followed by methane production, an established p

How do regions change their development path? We contribute to the growing literature on agency in regional development by combining it with a focus on the institutions that shape, support and constrain change agency in pursuit of different types of development paths. We answer the call for micro-level perspectives on regional economic change, using an in-depth and comparative case study approach.

Given population aging and the emphasis on in-home care, more working-age adults face demands of providing unpaid care to the elderly with potential implications for their wellbeing. Such effects likely vary across Europe because care is differently organized with more or less public support, dependence on family, and orientation toward gender equality. We studied the relationship between unpaid c

IntroductionChildren affected by Paediatric Feeding Disorder (PFD) cannot consume enough nourishment by mouth. PFD is highly prevalent and can affect the child's growth and development as well as family life.AimTo illuminate Swedish parents’ experiences of living with a child with PFD.MethodSemi-structured interviews via telephone or video calls were conducted with 14 purposefully recruited mother

Industries and regional economies evolve as a result of the interplay between local and non-local factors. Increasing globalization of both production- and innovation activities implies a shift in the relevant scales of interaction from the local towards the global level. This paper is concerned with the implications of such scale shifts for the role of the region and for cluster-related regional

Global production rates of metals vary from iron at 1.4 billion ton per year to platinum with 200 ton per year. Resource scarcity starts to manifest itself in rising prices and supply limitations, and metal substitution has been a major argument among economists when putting considerations of resource scarcity aside. Here we investigate the potential limits to metal substitution. Present consumpti