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Rigid-rod polymers tethered with delocalized anions and flexible ion conductive side chains present a synthetic pathway towards thin, single-ion conducting electrolyte membranes with low bulk resistance and high mechanical stability. In the present work we have synthesized poly(p-phenylene) (PpP) copolymers carrying lithium trifluoromethanesulfonimide groups and tetra(ethylene oxide) side chains t
