Direct visual evidence for the chemical mechanism of surface-enhanced resonance Raman scattering via charge transfer: (II) Binding-site and quantum-size effects
We describe quantum-size and binding-site effects on the chemical and local field enhancement mechanisms of surface-enhanced resonance Raman scattering (SERRS), in which the pyridine molecule is adsorbed on one of the vertices of the Ag-20 tetrahedron. We first investigated the influence of the binding site on normal Raman scattering (NRS) and excited state properties of optical absorption spectro
